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Giliomee, J.; du Toit, L. C.; Kumar, P.; Klumperman, B.; Choonara, Y. E. Evaluation of Composition Effects on the Physicochemical and Biological Properties of Polypeptide-Based Hydrogels for Potential Application in Wound Healing. Polymers (Basel, Switz.) 2021, 13 (11), 1828. https://doi.org/10.3390/polym13111828.
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Jharimune, S.; Pfukwa, R.; Chen, Z.; Anderson, J.; Klumperman, B.; Rioux, R. M. Chemical Identity of Poly(N-Vinylpyrrolidone) End Groups Impact Shape Evolution During the Synthesis of Ag Nanostructures. J. Am. Chem. Soc. 2021, 143 (1), 184–195. https://doi.org/10.1021/jacs.0c08528.
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Ball, L. E.; Riley, L. J.; Hadasha, W.; Pfukwa, R.; Smith, C. J. I.; Dafforn, T. R.; Klumperman, Bert. Influence of DIBMA Polymer Length on Lipid Nanodisc Formation and Membrane Protein Extraction. Biomacromolecules 2021, 22 (2), 763–772. https://doi.org/10.1021/acs.biomac.0c01538.
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Lakay, E.; Hermans, S.; Koch, K.; Klumperman, Bert. The Efficient Recovery of Au(III) Ions from Acidic Solutions by a Novel Scavenger Based on Functionalized Poly(Styrene-Co-Maleimide) Nanoparticles. Chem. Eng. J. (Amsterdam, Neth.) 2021, 414 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 128761. https://doi.org/10.1016/j.cej.2021.128761.
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Xia, Y.; Wei, J.; Zhao, S.; Guo, B.; Meng, F.; Klumperman, B.; Zhong, Zhiyuan. Systemic Administration of Polymersomal Oncolytic Peptide LTX-315 Combining with CpG Adjuvant and Anti-PD-1 Antibody Boosts Immunotherapy of Melanoma. J. Controlled Release 2021, 336 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 262–273. https://doi.org/10.1016/j.jconrel.2021.06.032.
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Hutchinson, R. A.; Klumperman, B.; Russell, G. T.; Van Herk, A. M. The Contributions of Prof. Kenneth F. O’Driscoll to Radical Copolymerization Kinetics. Can. J. Chem. Eng. 2021, No. Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved., Ahead of Print. https://doi.org/10.1002/cjce.24137.
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Grime, R. L.; Logan, R. T.; Nestorow, S. A.; Sridhar, P.; Edwards, P. C.; Tate, C. G.; Klumperman, B.; Dafforn, T. R.; Poyner, D. R.; Reeves, P. J.; Wheatley, Mark. Differences in SMA-like Polymer Architecture Dictate the Conformational Changes Exhibited by the Membrane Protein Rhodopsin Encapsulated in Lipid Nano-Particles. Nanoscale 2021, 13 (31), 13519–13528. https://doi.org/10.1039/d1nr02419a.
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Barnard, E.; Pfukwa, R.; Maiz, J.; Muller, A. J.; Klumperman, Bert. Synthesis, Structure, and Crystallization Behavior of Amphiphilic Heteroarm Molecular Brushes with Crystallizable Poly(Ethylene Oxide) and n-Alkyl Side Chains. Macromolecules (Washington, DC, U. S.) 2020, 53 (5), 1585–1595. https://doi.org/10.1021/acs.macromol.9b02473.
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Klumperman, B.; Heuts, J. P. A. The Solution Copolymerization of Styrene and Maleic Anhydride in a Continuous Stirred Tank Reactor and Its Theoretical Modelling. Polymer 2020, 202 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 122730. https://doi.org/10.1016/j.polymer.2020.122730.
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Cunningham, R. D.; Kopf, A. H.; Elenbaas, B. O. W.; Staal, B. B. P.; Pfukwa, R.; Killian, J. A.; Klumperman, Bert. Iterative RAFT-Mediated Copolymerization of Styrene and Maleic Anhydride toward Sequence- and Length-Controlled Copolymers and Their Applications for Solubilizing Lipid Membranes. Biomacromolecules 2020, 21 (8), 3287–3300. https://doi.org/10.1021/acs.biomac.0c00736.
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Fortuin, L.; Leshabane, M.; Pfukwa, R.; Coertzen, D.; Birkholtz, L.-M.; Klumperman, Bert. Facile Route to Targeted, Biodegradable Polymeric Prodrugs for the Delivery of Combination Therapy for Malaria. ACS Biomater. Sci. Eng. 2020, 6 (11), 6217–6227. https://doi.org/10.1021/acsbiomaterials.0c01234.
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Jokonya, S.; Langlais, M.; Leshabane, M.; Reader, P. W.; Vosloo, J. A.; Pfukwa, R.; Coertzen, D.; Birkholtz, L.-M.; Rautenbach, M.; Klumperman, Bert. Poly(N-Vinylpyrrolidone) Antimalaria Conjugates of Membrane-Disruptive Peptides. Biomacromolecules 2020, 21 (12), 5053–5066. https://doi.org/10.1021/acs.biomac.0c01202.
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Cloete, W. J.; Hayward, S.; Swart, P.; Klumperman, Bert. Degradation of Proteins and Starch by Combined Immobilization of Protease, α-Amylase and β-Galactosidase on a Single Electrospun Nanofibrous Membrane. Molecules 2019, 24 (3), 508/1-508/9. https://doi.org/10.3390/molecules24030508.
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Heyns, I. M.; Pfukwa, R.; Bertossi, L.; Ball, L. E.; Kelland, M. A.; Klumperman, Bert. Thermoresponsive Behavior of Poly(3-Methylene-2-Pyrrolidone) Derivatives. Eur. Polym. J. 2019, 112 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 714–721. https://doi.org/10.1016/j.eurpolymj.2018.10.040.
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Overduin, M.; Klumperman, Bert. Advancing Membrane Biology with Poly(Styrene-Co-Maleic Acid)-Based Native Nanodiscs. Eur. Polym. J. 2019, 110 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 63–68. https://doi.org/10.1016/j.eurpolymj.2018.11.015.
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Kargaard, A.; Sluijter, J. P. G.; Klumperman, Bert. Polymeric SiRNA Gene Delivery - Transfection Efficiency versus Cytotoxicity. J. Controlled Release 2019, 316 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 263–291. https://doi.org/10.1016/j.jconrel.2019.10.046.
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Phiri, M. M.; Hadasha, W.; Pfukwa, R.; Klumperman, Bert. Synthesis and Characterization of Liquid Molecular Brush Binder for Coating Applications. Eur. Polym. J. 2018, 102 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 178–186. https://doi.org/10.1016/j.eurpolymj.2018.03.023.
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Mbizana, S.; Hlalele, L.; Pfukwa, R.; Du Toit, A.; Lumkwana, D.; Loos, B.; Klumperman, Bert. Synthesis and Cell Interaction of Statistical L-Arginine-Glycine-L-Aspartic Acid Terpolypeptides. Biomacromolecules 2018, 19 (7), 3058–3066. https://doi.org/10.1021/acs.biomac.8b00620.
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Zhang, Q.; Heyns, I. M.; Pfukwa, R.; Klumperman, B.; Kelland, M. A. Improving the Kinetic Hydrate Inhibition Performance of 3-Methylene-2-Pyrrolidone Polymers by N-Alkylation, Ring Expansion, and Copolymerization. Energy Fuels 2018, 32 (12), 12337–12344. https://doi.org/10.1021/acs.energyfuels.8b03103.
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Hall, S. C. L.; Tognoloni, C.; Price, G. J.; Klumperman, B.; Edler, K. J.; Dafforn, T. R.; Arnold, Thomas. Influence of Poly(Styrene-Co-Maleic Acid) Copolymer Structure on the Properties and Self-Assembly of SMALP Nanodiscs. Biomacromolecules 2018, 19 (3), 761–772. https://doi.org/10.1021/acs.biomac.7b01539.
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Kemp, R.; Klumperman, B.; Gule, N. Prudence. Novel Core-Sheath Antimicrobial Nanofibrous Mats. J. Appl. Polym. Sci. 2018, 135 (22), n/a. https://doi.org/10.1002/app.46303.
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Kriel, J.; Muller-Nedebock, K.; Maarman, G.; Mbizana, S.; Ojuka, E.; Klumperman, B.; Loos, Ben. Coordinated Autophagy Modulation Overcomes Glioblastoma Chemoresistance through Disruption of Mitochondrial Bioenergetics. Sci. Rep. 2018, 8 (1), 1–13. https://doi.org/10.1038/s41598-018-28590-9.
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Klumperman, L.; Pfukwa, R.; Heyns, I. Marie. Synthesis of 3-Methylene-2-Pyrrolidone Based Polymers., February 22, 2017.
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Weideman, I.; Pfukwa, R.; Klumperman, Bert. Phosphazene Base Promoted Anionic Polymerization of N-Butyraldehyde. Eur. Polym. J. 2017, 93 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 97–102. https://doi.org/10.1016/j.eurpolymj.2017.05.034.
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Hlalele, L.; Pfukwa, R.; Klumperman, Bert. Simulation Studies of the Discrete Semi-Batch RAFT-Mediated Polymerization of Styrene Using a RAFT Agent with Relatively Poor Leaving Group. Eur. Polym. J. 2017, 95 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 596–605. https://doi.org/10.1016/j.eurpolymj.2017.08.053.
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Cloete, W. J.; Klumperman, B.; Cloete, T. Eugene. Increased Functionality Through Surface Grafting: Polymeric Surfaces. Curr. Org. Chem. 2017, 21 (24), 2455–2465. https://doi.org/10.2174/1385272821666170620112440.
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Abrahamsen, E.; Heyns, I. M.; von Solms, N.; Pfukwa, R.; Klumperman, B.; Kelland, M. A. First Study of Poly(3-Methylene-2-Pyrrolidone) as a Kinetic Hydrate Inhibitor. Energy Fuels 2017, 31 (12), 13572–13577. https://doi.org/10.1021/acs.energyfuels.7b03006.
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Heyns, I. M.; Pfukwa, R.; Klumperman, Bert. Synthesis, Characterization, and Evaluation of Cytotoxicity of Poly(3-Methylene-2-Pyrrolidone). Biomacromolecules 2016, 17 (5), 1795–1800. https://doi.org/10.1021/acs.biomac.6b00210.
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Giliomee, J.; Pfukwa, R.; Gule, N. P.; Klumperman, Bert. Smart Block Copolymers of PVP and an Alkylated PVP Derivative: Synthesis, Characterization, Thermoresponsive Behaviour and Self-Assembly. Polym. Chem. 2016, 7 (5), 1138–1146. https://doi.org/10.1039/C5PY01609F.
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Reader, Paul. W.; Pfukwa, R.; Jokonya, S.; Arnott, G. E.; Klumperman, Bert. Synthesis of α,ω-Heterotelechelic PVP for Bioconjugation, via a One-Pot Orthogonal End-Group Modification Procedure. Polym. Chem. 2016, 7 (42), 6450–6456. https://doi.org/10.1039/C6PY01296E.
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Rowan, S. J.; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Grubbs, R. B.; Hillmyer, M. A.; Hutchings, L. R.; Mahanthappa, M. K.; O’Reilly, R. K.; Ouchi, M.; Sawamoto, M.; Lodge, T. P. Discussion on “Aperiodic Copolymers”. ACS Macro Lett. 2016, 5 (1), 1–3. https://doi.org/10.1021/acsmacrolett.5b00758.
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Gule, N. P.; Begum, N. M.; Klumperman, Bert. Advances in Biofouling Mitigation: A Review. Crit. Rev. Environ. Sci. Technol. 2016, 46 (6), 535–555. https://doi.org/10.1080/10643389.2015.1114444.
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Swanepoel, A.; du Preez, I.; Mahlangu, T.; Chetty, A.; Klumperman, B. Development of Bioconjugated Dye-Doped Poly(Styrene-Co-Maleimide) Nanoparticles as a New Bioprobe. J. Mater. Chem. B 2015, 3 (13), 2635–2640. https://doi.org/10.1039/C4TB01520G.
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Du Prez, F.; Hoogenboom, R.; Klumperman, B.; Meier, M.; Monteiro, M.; Muller, A.; Vancso, Julius. Fifty Years of Polymer Science. Eur. Polym. J. 2015, 65 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 3. https://doi.org/10.1016/j.eurpolymj.2015.02.017.
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van Wijk, J.; Salari, J. W. O.; Meuldijk, J.; Klumperman, Bert. Determination of the Shell Growth Direction during the Formation of Silica Microcapsules by Confocal Fluorescence Microscopy. J. Mater. Chem. B 2015, 3 (39), 7745–7751. https://doi.org/10.1039/C5TB01232E.
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Vermonden, T.; Klumperman, Bert. The Past, Present and Future of Hydrogels. Eur. Polym. J. 2015, 72 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 341–343. https://doi.org/10.1016/j.eurpolymj.2015.08.032.
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Ilchev, A.; Pfukwa, R.; Hlalele, L.; Smit, M.; Klumperman, Bert. Improved Control through a Semi-Batch Process in RAFT-Mediated Polymerization Utilizing Relatively Poor Leaving Groups. Polym. Chem. 2015, 6 (46), 7945–7948. https://doi.org/10.1039/C5PY01293G.
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Klumperman, Bert. The Rationale behind Sequence-Controlled Maleimide Copolymers. ACS Symp. Ser. 2014, 1170 (Sequence-Controlled Polymers: Synthesis, Self-Assembly, and Properties), 213–221. https://doi.org/10.1021/bk-2014-1170.ch014.
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Klumperman, Bert. Living Radical Polymerization. In Encycl. Polym. Sci. Technol. (4th Ed.); John Wiley & Sons, Inc., 2014; Vol. 7, pp 648–673.
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van Wijk, J.; van Deventer, N.; Harmzen, E.; Meuldijk, J.; Klumperman, Bert. Formation of Hybrid Poly(Styrene-Co-Maleic Anhydride)-Silica Microcapsules. J. Mater. Chem. B 2014, 2 (30), 4826–4835. https://doi.org/10.1039/C4TB00473F.
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van Wijk, J.; Heunis, T.; Harmzen, E.; Dicks, L. M. T.; Meuldijk, J.; Klumperman, Bert. Compartmentalization of Bacteria in Microcapsules. Chem. Commun. (Cambridge, U. K.) 2014, 50 (97), 15427–15430. https://doi.org/10.1039/C4CC04901B.
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Hadasha, W.; Klumperman, Bert. Atom Transfer Radical Polymerization as a Powerful Tool in the Synthesis of Molecular Brushes. Polym. Int. 2014, 63 (5), 824–834. https://doi.org/10.1002/pi.4697.
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Salari, J. W. O.; Mutsaers, G.; Meuldijk, J.; Klumperman, Bert. Deformation of the Water/Oil Interface during the Adsorption of Sterically Stabilized Particles. Langmuir 2014, 30 (25), 7327–7333. https://doi.org/10.1021/la501334p.
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Reader, P. W.; Klumperman, Bert. Hetero Bi-Functional Polymer-Polypeptide Conjugates. In Abstracts of Papers, 248th ACS National Meeting & Exposition, San Francisco, CA, United States, August 10-14, 2014; American Chemical Society, 2014; p POLY-653.
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Gule, N. P.; de Kwaadsteniet, M.; Cloete, T. E.; Klumperman, Bert. Furanone-Containing Poly(Vinyl Alcohol) Nanofibers for Cell-Adhesion Inhibition. Water Res. 2013, 47 (3), 1049–1059. https://doi.org/10.1016/j.watres.2012.11.012.
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Cloete, W. J.; Verwey, L.; Klumperman, Bert. Permanently Antimicrobial Waterborne Coatings Based on the Dual Role of Modified Poly(Styrene-Co-Maleic Anhydride). Eur. Polym. J. 2013, 49 (5), 1080–1088. https://doi.org/10.1016/j.eurpolymj.2013.01.012.
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van Wijk, J.; Salari, J. W. O.; Zaquen, N.; Meuldijk, J.; Klumperman, Bert. Poly(Methyl Methacrylate)-Silica Microcapsules Synthesized by Templating Pickering Emulsion Droplets. J. Mater. Chem. B 2013, 1 (18), 2394–2406. https://doi.org/10.1039/c3tb20175a.
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Shi, Y.; van den Dungen, E. T. A.; Klumperman, B.; van Nostrum, C. F.; Hennink, W. E. Reversible Addition-Fragmentation Chain Transfer Synthesis of a Micelle-Forming, Structure Reversible Thermosensitive Diblock Copolymer Based on the N-(2-Hydroxy Propyl) Methacrylamide Backbone. ACS Macro Lett. 2013, 2 (5), 403–408. https://doi.org/10.1021/mz300662b.
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Boyer, C.; Klumperman, Bert. Preface. Eur. Polym. J. 2013, 49 (10), 2859–2860. https://doi.org/10.1016/j.eurpolymj.2013.07.001.
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Colquhoun, H.; Klumperman, Bert. Self-Healing Polymers. Polym. Chem. 2013, 4 (18), 4832–4833. https://doi.org/10.1039/c3py90046k.