Department of

Chemistry & Polymer Science

Publications 2016

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Ahire, J. J.; Robertson, D.; Neveling, D. P.; van Reenen, A. J.; Dicks, L. M. T. Hyaluronic Acid-Coated Poly(D,L-Lactide) (PDLLA) Nanofibers Prepared by Electrospinning and Coating. RSC Adv. 2016, 6 (41), 34791–34796. https://doi.org/10.1039/C6RA01996J.
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Applewhite, M. J.; Haynes, D. A.; Arnott, G. E. Cyanocalix[4]Arenes: Synthesis, Crystal Structures and Reactivity Studies. Supramol. Chem. 2016, 28 (5–6), 475–484. https://doi.org/10.1080/10610278.2015.1121268.
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Baartzes, N.; Stringer, T.; Chellan, P.; Combrinck, J. M.; Smith, P. J.; Hutton, A. T.; Smith, G. S. Synthesis, Characterization, Antiplasmodial Evaluation and Electrochemical Studies of Water-Soluble Heterobimetallic Ferrocenyl Complexes. Inorg. Chim. Acta 2016, 446 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 111–115. https://doi.org/10.1016/j.ica.2016.02.058.
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Bhatt, P. M.; Belmabkhout, Y.; Cadiau, A.; Adil, K.; Shekhah, O.; Shkurenko, A.; Barbour, L. J.; Eddaoudi, Mohamed. A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO2 Removal and Air Capture Using Physisorption. J. Am. Chem. Soc. 2016, 138 (29), 9301–9307. https://doi.org/10.1021/jacs.6b05345.
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Bhatt, P. M.; Batisai, E.; Smith, V. J.; Barbour, L. J. Creation of New Guest Accessible Space under Gas Pressure in a Flexible MOF: Multidimensional Insight through Combination of in Situ Techniques. Chem. Commun. (Cambridge, U. K.) 2016, 52 (76), 11374–11377. https://doi.org/10.1039/C6CC06709C.
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Blackie, M. A. L.; Feng, T.-S.; Smith, P. J.; Chibale, Kelly. Synthesis of Novel β-Lactams and in Vitro Evaluation against the Human Malaria Parasite Plasmodium Falciparum. ARKIVOC (Gainesville, FL, U. S.) 2016, No. 3, 214–235. https://doi.org/10.3998/ark.5550190.p009.465.
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Brigg, S.; Pribut, N.; Basson, A. E.; Avgenikos, M.; Venter, R.; Blackie, M. A.; van Otterlo, W. A. L.; Pelly, S. C. Novel Indole Sulfides as Potent HIV-1 NNRTIs. Bioorg. Med. Chem. Lett. 2016, 26 (6), 1580–1584. https://doi.org/10.1016/j.bmcl.2016.02.006.
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Burgoyne, A. R.; Kaschula, C. H.; Parker, M. I.; Smith, G. S. In Vitro Cytotoxicity of Half-Sandwich Platinum Group Metal Complexes of a Cationic Alkylated Phosphaadamantane Ligand. Eur. J. Inorg. Chem. 2016, 2016 (8), 1267–1273. https://doi.org/10.1002/ejic.201501458.
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de Villiers, A.; Venter, P.; Pasch, Harald. Recent Advances and Trends in the Liquid-Chromatography-Mass Spectrometry Analysis of Flavonoids. J. Chromatogr. A 2016, 1430 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 16–78. https://doi.org/10.1016/j.chroma.2015.11.077.
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Domagala, S.; Haynes, D. A. Experimental and Theoretical Charge Density Assessments for the 4-Perfluoropyridyl- and 4-Perflurophenyl-1,2,3,5-Dithiadiazolyl Radicals. CrystEngComm 2016, 18 (37), 7116–7125. https://doi.org/10.1039/C6CE01095D.
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Engel, E. R.; Smith, V. J.; Bezuidenhout, C. X.; Barbour, L. J. Thermoresponsive Organic Inclusion Compounds: Modification of Thermal Expansion Behavior by Simple Guest Replacement. Chem. Mater. 2016, 28 (14), 5073–5079. https://doi.org/10.1021/acs.chemmater.6b01916.
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Esterhuysen, C.; Ford, T. Anthony. Ab Initio Studies of the Structures and Vibrational Spectra of the Hydrogen Halide and Lithium Halide Homo- and Heterodimers and Some Mixed Hydrogen Halide/Lithium Halide Heterodimers. Theor. Chem. Acc. 2016, 135 (9), 1–15. https://doi.org/10.1007/s00214-016-1949-y.
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Giliomee, J.; Pfukwa, R.; Gule, N. P.; Klumperman, Bert. Smart Block Copolymers of PVP and an Alkylated PVP Derivative: Synthesis, Characterization, Thermoresponsive Behaviour and Self-Assembly. Polym. Chem. 2016, 7 (5), 1138–1146. https://doi.org/10.1039/C5PY01609F.
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Gosset, M.; Hamy, A.-S.; Mallon, P.; Delomenie, M.; Mouttet, D.; Pierga, J.-Y.; Lae, M.; Fourquet, A.; Rouzier, R.; Reyal, F.; Feron, J.-Guillaume. Prognostic Impact of Time to Ipsilateral Breast Tumor Recurrence after Breast Conserving Surgery. PLoS One 2016, 11 (8), e0159888/1-e0159888/16. https://doi.org/10.1371/journal.pone.0159888.
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Greyling, G.; Pasch, Harald. Multidetector Thermal Field-Flow Fractionation: A Unique Tool for Monitoring the Structure and Dynamics of Block Copolymer Micelles. Macromolecules (Washington, DC, U. S.) 2016, 49 (5), 1882–1889. https://doi.org/10.1021/acs.macromol.5b02634.
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Groenewald, F.; Esterhuysen, C.; Dillen, Jan. Electrostatic Surface Potential Analysis of the I-3 Ion in the Gas Phase, the Condensed Phase and a Novel Extrapolation to the Solid State. Comput. Theor. Chem. 2016, 1090 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 225–233. https://doi.org/10.1016/j.comptc.2016.06.026.
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Groenewald, F.; Dillen, J.; Raubenheimer, H. G.; Esterhuysen, Catharine. Preparing Gold(I) for Interactions with Proton Donors: The Elusive [Au]···HO Hydrogen Bond. Angew. Chem., Int. Ed. 2016, 55 (5), 1694–1698. https://doi.org/10.1002/anie.201508358.
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Gule, N. P.; Begum, N. M.; Klumperman, Bert. Advances in Biofouling Mitigation: A Review. Crit. Rev. Environ. Sci. Technol. 2016, 46 (6), 535–555. https://doi.org/10.1080/10643389.2015.1114444.
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Heyns, I. M.; Pfukwa, R.; Klumperman, Bert. Synthesis, Characterization, and Evaluation of Cytotoxicity of Poly(3-Methylene-2-Pyrrolidone). Biomacromolecules 2016, 17 (5), 1795–1800. https://doi.org/10.1021/acs.biomac.6b00210.
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Janiak, A.; Petryk, M.; Barbour, L. J.; Kwit, Marcin. Readily Prepared Inclusion Forming Chiral Calixsalens. Org. Biomol. Chem. 2016, 14 (2), 669–673. https://doi.org/10.1039/C5OB02090E.
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John, S. V.; Mayedwa, N.; Ikpo, C.; Molefe, L. Y.; Ndipingwi, M. M.; Dywili, N. R.; Van Wyk, J.; Mapolie, S. F.; Baker, P.; Iwuoha, Emmanuel. Photoluminescence Quenching of Poly(Octylfluorenylbenzothiadiazole) Luminophore by n-Type Cobalt(II) Salicylaldimine Metallodendrimer. Synth. Met. 2016, 220 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 114–122. https://doi.org/10.1016/j.synthmet.2016.05.031.
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Kane, C. M.; Banisafar, A.; Dougherty, T. P.; Barbour, L. J.; Holman, K. Travis. Enclathration and Confinement of Small Gases by the Intrinsically 0D Porous Molecular Solid, Me,H,SiMe2. J. Am. Chem. Soc. 2016, 138 (13), 4377–4392. https://doi.org/10.1021/jacs.5b11395.
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Kaschula, C. H.; Hunter, R.; Cotton, J.; Tuveri, R.; Ngarande, E.; Dzobo, K.; Schaefer, G.; Siyo, V.; Lang, D.; Kusza, D. A.; Davies, B.; Katz, A. A.; Parker, M. Iqbal. The Garlic Compound Ajoene Targets Protein Folding in the Endoplasmic Reticulum of Cancer Cells. Mol. Carcinog. 2016, 55 (8), 1213–1228. https://doi.org/10.1002/mc.22364.
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Kim, S.-H.; Kaschula, C. H.; Priedigkeit, N.; Lee, A. V.; Singh, S. V. Forkhead Box Q1 Is a Novel Target of Breast Cancer Stem Cell Inhibition by Diallyl Trisulfide. J. Biol. Chem. 2016, 291 (26), 13495–13508. https://doi.org/10.1074/jbc.M116.715219.
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Koch, K. R.; Cursiefen, C.; Heindl, L. M.; Trester, W.; Trester, M.; Muller-Uri, N. Ocular Prosthetics. Fitting, Daily Use and Complications. Ophthalmologe 2016, 113 (2), 133–142.
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Kuter, D.; Mohunlal, R.; Fitzroy, S.-M.; Asher, C.; Smith, P. J.; Egan, T. J.; de Villiers, K. A. Insights into the Initial Stages of Lipid-Mediated Haemozoin Nucleation. CrystEngComm 2016, 18 (27), 5177–5187. https://doi.org/10.1039/C6CE00866F.
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Laas, E.; Mallon, P.; Duhoux, F. P.; Hamidouche, A.; Rouzier, R.; Reyal, Fabien. Low Concordance between Gene Expression Signatures in ER Positive HER2 Negative Breast Carcinoma Could Impair Their Clinical Application. PLoS One 2016, 11 (2), e0148957/1-e0148957/12. https://doi.org/10.1371/journal.pone.0148957.
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Lama, P.; Aggarwal, H.; Bezuidenhout, C. X.; Barbour, L. J. Giant Hysteretic Sorption of CO2: In Situ Crystallographic Visualization of Guest Binding within a Breathing Framework at 298 K. Angew. Chem., Int. Ed. 2016, 55 (42), 13271–13275. https://doi.org/10.1002/anie.201607076.
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Lama, P.; Alimi, L. O.; Das, R. K.; Barbour, L. J. Hydration-Dependent Anomalous Thermal Expansion Behaviour in a Coordination Polymer. Chem. Commun. (Cambridge, U. K.) 2016, 52 (15), 3231–3234. https://doi.org/10.1039/C6CC00158K.
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Le Roux, A.; Dobrzanska, L.; Raubenheimer, H. G.; Luckay, R. C. Oxo Complexes of Mo(VI) and W(VI) with α-Alkoxycarboxylate Ligands: The Role of Counterions and Water of Crystallization. J. Mol. Struct. 2016, 1117 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 113–120. https://doi.org/10.1016/j.molstruc.2016.03.050.
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Makan, A. C.; Williams, R. P.; Pasch, Harald. Field Flow Fractionation for the Size, Molar Mass, and Gel Content Analysis of Emulsion Polymers for Water-Based Coatings. Macromol. Chem. Phys. 2016, 217 (18), 2027–2040. https://doi.org/10.1002/macp.201600208.
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Makan, A. C.; Spallek, M. J.; du Toit, M.; Klein, T.; Pasch, Harald. Advanced Analysis of Polymer Emulsions: Particle Size and Particle Size Distribution by Field-Flow Fractionation and Dynamic Light Scattering. J. Chromatogr. A 2016, 1442 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 94–106. https://doi.org/10.1016/j.chroma.2016.03.013.
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Malik, M. I.; Pasch, Harald. Field-Flow Fractionation: New and Exciting Perspectives in Polymer Analysis. Prog. Polym. Sci. 2016, 63 (Copyright (C) 2021 American Chemical Society (ACS). All Rights Reserved.), 42–85. https://doi.org/10.1016/j.progpolymsci.2016.03.004.
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Masi, M.; Cala, A.; Tabanca, N.; Cimmino, A.; Green, I. R.; Bloomquist, J. R.; van Otterlo, W. A. L.; Macias, F. A.; Evidente, Antonio. Alkaloids with Activity against the Zika Virus Vector Aedes Aegypti (L.)-Crinsarnine and Sarniensinol, Two New Crinine and Mesembrine Type Alkaloids Isolated from the South African Plant Nerine Sarniensis. Molecules 2016, 21 (11), 1432/1-1432/11. https://doi.org/10.3390/molecules21111432.
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Mbatha, L.; Chakravorty, S.; de Koning, C. B.; van Otterlo, W. A. L.; Arbuthnot, P.; Ariatti, M.; Singh, Moganavelli. Spacer Length: A Determining Factor in the Design of Galactosyl Ligands for Hepatoma Cell-Specific Liposomal Gene Delivery. Curr. Drug Delivery 2016, 13 (6), 935–945. https://doi.org/10.2174/1567201813666160224123450.
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Medellin, D. C.; Zhou, Q.; Scott, R.; Hill, R. M.; Frail, S. K.; Dasari, R.; Ontiveros, S. J.; Pelly, S. C.; van Otterlo, W. A. L.; Betancourt, T.; Shuster, C. B.; Hamel, E.; Bai, R.; LaBarbera, D. V.; Rogelj, S.; Frolova, L. V.; Kornienko, Alexander. Novel Microtubule-Targeting 7-Deazahypoxanthines Derived from Marine Alkaloid Rigidins with Potent in Vitro and in Vivo Anticancer Activities. J. Med. Chem. 2016, 59 (1), 480–485. https://doi.org/10.1021/acs.jmedchem.5b01426.
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Meli, A.; Macedi, E.; De Riccardis, F.; Smith, V. J.; Barbour, L. J.; Izzo, I.; Tedesco, Consiglia. Solid-State Conformational Flexibility at Work: Zipping and Unzipping within a Cyclic Peptoid Single Crystal. Angew. Chem., Int. Ed. 2016, 55 (15), 4679–4682. https://doi.org/10.1002/anie.201511053.
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Mketo, N.; Jordaan, J. H. L.; Jordaan, A.; Swarts, A. J.; Mapolie, S. F. Synthesis, Characterization, and Catalytic Application of Mononuclear and Dendritic Cationic CuI Iminopyridine-Ligated Complexes in Aryl Iodide Hydroxylation. Eur. J. Inorg. Chem. 2016, 2016 (23), 3781–3790. https://doi.org/10.1002/ejic.201600417.
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Murima, D.; Pfukwa, H.; Tiggelman, I.; Hartmann, P. C.; Pasch, Harald. Novel Polymer Clay-Based Nanocomposites: Films with Remarkable Optical and Water Vapor Barrier Properties. Macromol. Mater. Eng. 2016, 301 (7), 836–845. https://doi.org/10.1002/mame.201600080.
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Ndiripo, A.; Joubert, D.; Pasch, Harald. Ethylene/1-Heptene Copolymers as Interesting Alternatives to 1-Octene-Based LLDPE: Molecular Structure and Physical Properties. J. Polym. Sci., Part A: Polym. Chem. 2016, 54 (7), 962–975. https://doi.org/10.1002/pola.27932.
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Panayides, J.-L.; Mathieu, V.; Banuls, L. M. Y.; Apostolellis, H.; Dahan-Farkas, N.; Davids, H.; Harmse, L.; Rey, M. E. C.; Green, I. R.; Pelly, S. C.; Kiss, R.; Kornienko, A.; van Otterlo, W. A. L. Synthesis and in Vitro Growth Inhibitory Activity of Novel Silyl- and Trityl-Modified Nucleosides. Bioorg. Med. Chem. 2016, 24 (12), 2716–2724. https://doi.org/10.1016/j.bmc.2016.04.036.
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Phiri, M. J.; Pasch, Harald. Exploring the Compositional Heterogeneity of Vis-Broken Impact Poly(Propylene) Copolymers by Advanced Fractionation Methods. Macromol. Chem. Phys. 2016, 217 (6), 783–793. https://doi.org/10.1002/macp.201500470.
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Pribut, N.; Veale, C. G. L.; Basson, A. E.; van Otterlo, W. A. L.; Pelly, S. C. Application of the Huisgen Cycloaddition and “click” Reaction toward Various 1,2,3-Triazoles as HIV Non-Nucleoside Reverse Transcriptase Inhibitors. Bioorg. Med. Chem. Lett. 2016, 26 (15), 3700–3704. https://doi.org/10.1016/j.bmcl.2016.05.082.
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Reader, Paul. W.; Pfukwa, R.; Jokonya, S.; Arnott, G. E.; Klumperman, Bert. Synthesis of α,ω-Heterotelechelic PVP for Bioconjugation, via a One-Pot Orthogonal End-Group Modification Procedure. Polym. Chem. 2016, 7 (42), 6450–6456. https://doi.org/10.1039/C6PY01296E.
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Rowan, S. J.; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Grubbs, R. B.; Hillmyer, M. A.; Hutchings, L. R.; Mahanthappa, M. K.; O’Reilly, R. K.; Ouchi, M.; Sawamoto, M.; Lodge, T. P. Discussion on “Aperiodic Copolymers”. ACS Macro Lett. 2016, 5 (1), 1–3. https://doi.org/10.1021/acsmacrolett.5b00758.
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Smith, M.; Hunter, R.; Stellenboom, N.; Kusza, D. A.; Parker, M. I.; Hammouda, A. N. H.; Jackson, G.; Kaschula, C. H. The Cytotoxicity of Garlic-Related Disulphides and Thiosulfonates in WHCO1 Oesophageal Cancer Cells Is Dependent on S-Thiolation and Not Production of ROS. Biochim. Biophys. Acta, Gen. Subj. 2016, 1860 (7), 1439–1449. https://doi.org/10.1016/j.bbagen.2016.03.032.
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Tedesco, C.; Meli, A.; Macedi, E.; Iuliano, V.; Ricciardulli, A. G.; De Riccardis, F.; Vaughan, G. B. M.; Smith, V. J.; Barbour, L. J.; Izzo, Irene. Ring Size Effect on the Solid State Assembly of Propargyl Substituted Hexa- and Octacyclic Peptoids. CrystEngComm 2016, 18 (46), 8838–8848. https://doi.org/10.1039/C6CE01800A.
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van Heerden, D. P.; Esterhuysen, C.; Barbour, L. J. Elucidating the Mechanism Responsible for Anomalous Thermal Expansion in a Metal-Organic Framework. Dalton Trans. 2016, 45 (10), 4141–4149. https://doi.org/10.1039/C5DT01927C.
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van Niekerk, D. M. E.; Gerber, W. J.; Koch, K. R. A DFT Study to Unravel the Ligand Exchange Kinetics and Thermodynamics of OsVIII Oxo/Hydroxido/Aqua Complexes in Aqueous Matrices. Dalton Trans. 2016, 45 (16), 7028–7041. https://doi.org/10.1039/C6DT00657D.